含硫化物镁铁质-超镁铁质侵入体中橄榄石Mg、Ni含量的制约:原理、模式及Voisey's Bay侵入体样品研究(英文)   总被引：4，自引：0，他引：4  

李楚思  Edward M.Ripley 《地学前缘》2007,14(5):177-185

镁铁质-超镁铁质岩浆结晶分离早期形成镁铁矿物,镁铁矿物中的Ni和Mg是相容元素。随着结晶分离作用的进行,Ni、Mg在硅酸盐岩浆及后形成的硅酸盐物质中的丰度下降。橄榄石中Ni含量及硅酸盐物质MgO/FeO比值都与母岩浆的相关值相关,据此可推断母岩浆的信息,它们之间可由实验测得的系数相联系。当岩浆饱和硫化物时,在结晶分离过程中硫化物珠滴会与镁铁硅酸盐物质一道析出,同时,与硫化物非饱和岩浆相比,过多的Ni会随之析出。这也反映在Ni、Mg含量比无硫化物分离时有更迅速的降低上。Ni、Mg含量变化值可以在VoiseysBay侵入体的模式曲线上反映出,加拿大Labrador的这一侵入体赋存了一个世界级的Ni-Cu-Co硫化物矿床。过去的作法是将侵入体中橄榄石的Ni、Mg含量与Simkin和Smith得出的各种火成岩中橄榄石的Ni、Mg含量相比较以确定Ni亏损,进而假定橄榄石来自硫化物饱和、有经济价值的岩浆。现在的研究显示这种简单的对比会导致错误。将样品数据与模式曲线对比并反映出侵入体矿物结晶堆积特征是重要的方法。使用这一方法,样品数据能很好地被模式曲线拟合。以在VoiseysBay的研究为例,当硫化物液相与硅酸盐矿物被去除后,硫化物非饱和的分离作用期就会显现出来,随后是硅酸盐结晶作用期。  相似文献   

Campanian Climatic Change: Isotopic Evidence from Far East, North America, North Atlantic and Western Europe          下载免费PDF全文

Yuri D. Zakharov  Yasunari Shiget  Kazushige Tanabe  Yasuhiro I  Olga P. Smyshlyaev  Ekaterina A. Sokolov  Alexer M. Popov  Tatiana A. Velivetskay  Tamara B. Afanasyeva 《《地质学报》英文版》2007,81(6):1049-1069

Paleoclimatic settings have been reconstructed for the Campanian using original oxygen-isotopic analyses of well-preserved molluskan and foraminifera shells from Russian Far East, Hokkaido, USA, Belgium and some DSDP holes (95, 98, 102, 390A, and 392A) in North Atlantic. Early Early Campanian climatic optimum has been recognized from data on high bottom shelf water paleotemperatures in middle latitudes of both the western circum-Pacific (to 24.2°C) and the eastern circum-Pacific (to 26.4°C) areas and high bottom shallow water paleotemperatures in high latitudes of the Koryak Upland (22.4–25.5°C), which agrees with the data on the Campanian Barykovskaya flora in high latitudes (Golovneva and Herman, 1998) and Jonker flora and its equivalents in middle latitudes. Judging from the data on comparatively high bottom shallow water paleotemperature values in high latitudes, South Alaska (19.4°C) and the Koryak Upland (22.4–25.5°C), we also expect Latest Campanian temperature maximum, which has not been confirmed, however, for low and middle latitudes by neither of isotopic nor paleobotanic data now. Main climatic tendency during the Campanian (with the exception of Latest Campanian) has been learned from isotopic composition of Campanian aragonitic ammonoid shells from the Hokkaido-South Sakhalin (Krilyon) marine basin. In contrary to Huber’s et al. (2002) assumption, we expect warm greenhouse conditions during the most part of the Campanian.  相似文献   

斯堪的那维亚臭氧亏损和地面加热     

Zhou Libo  Zou Han  Ji Chongping  Wang Wei  Jian Yongxiao 《大气科学进展》2001,18(3):454-466

对ＮＡＳＡ的ＴＯＭＳ臭氧资料进行分析后指出：冬季在北极的斯堪的那维亚地区存在一个明显的臭氧亏损区，亏损区的中心值达－５０ ＤＵ，相当于该区域平均值的 １５％。对臭氧亏损和北大西洋海温的东西向差异作相关分析得到：其季节变化的相关系数为－０．９６，逐月（ １６８个月）变化的相关系数为－０．７０。同样对臭氧亏损与地面加热进行相关分析后指出：斯堪的那维亚地区的臭氧亏损和该地区地面的热通量关系极其密切，其相关系数均在－０．８７以上。由此我们认为：北大西洋暖流向北输送能量，引起斯堪的纳维亚地区地面加热，由此造成了冬季该地区的臭氧亏损。  相似文献   

南海北部1987～1988年颗粒物质和硅藻通量的季节性变化:季风气候与 El Nino的响应   总被引：2，自引：0，他引：2       下载免费PDF全文

郑玉龙  王汝建  郑连福  陈荣华  陈建芳 《第四纪研究》2001,21(4):359-365

南海北部1987年9月～1988年10月沉积物捕获器中颗粒物质和硅藻通量的季节性变化受到季风气候的控制.颗粒物质与硅藻在东北和西南季风盛行期增加,在季风转变期减少.浅层和深层的颗粒总通量、蛋白石通量、碳酸钙通量、蛋白石/颗粒总通量比值、碳酸钙/颗粒总通量比值、有机碳/磷的比值以及浅层硅藻Thalassionema nitzschioides、Coscinodiscus excentricus、Coscinodiscus nodulifer、Nitzschia marina和Rhizosolenia bergonii的通量在东北季风期间明显地增加了,这些变化可能与1987年～1988年发生的EINino事件相关.  相似文献   

High precision glacial–interglacial benthic foraminiferal Sr/Ca records from the eastern equatorial Atlantic Ocean and Caribbean Sea     

Chuan-Chou Shen  David W. Hastings  Typhoon Lee  Chin-Hsin Chiu  Meng-Yang Lee  Kuo-Yen Wei  R. Lawrence Edwards 《Earth and Planetary Science Letters》2001,190(3-4):197-209

Glacial–interglacial variation in the marine Sr/Ca ratio has important implications for coral Sr thermometry [J.W. Beck et al., Science 257 (1992) 644–647]. A possible variation of 1–3% was proposed based on ocean models [H.M. Stoll and D.P. Schrag, Geochim. Cosmochim. Acta 62 (1998) 1107–1118]. Subsequently, studies have used fossil foraminifera to test this prediction [P.A. Martin et al., Geochem. Geophys. Geosyst. 1 (1999); H.M. Stoll et al., Geochim. Cosmochim. Acta 63 (1999) 3535–3547; H. Elderfield et al., Geochem. Geophys. Geosyst. 1 (2000)]. But whether some component of foraminiferal Sr/Ca variation can be uniquely ascribed to seawater Sr variation is still not clear. To address this question, we developed cleaning and analysis techniques and measured Sr/Ca ratios on individual shells of the modern benthic foraminifer Cibicidoides wuellerstorfi. We showed that different size shells have different Sr/Ca ratios; however, samples with shell sizes of 355–500 μm appear to have normally distributed Sr/Ca ratios (1σ=1.8%). For multi-shell measurements (with estimated errors of 0.12–0.39%), the ratio varied by as much as 7.2±0.5% during the last glaciation for two Caribbean records at the same site and by 3.7±0.5% over the past 40,000 yr for one record from the Sierra Leone Rise in the eastern equatorial Atlantic. The two Caribbean records are very similar indicating that the behavior of shell Sr uptake was identical locally and that the shell Sr/Ca ratio faithfully reflects the local environment. The Atlantic record differs from the Caribbean records by as much as several percent. Thus, the foraminiferal Sr/Ca changes cannot be solely due to changes in seawater Sr/Ca unless the glacial deep ocean had spatial variation in Sr/Ca well in excess of the modern ocean. Certain similarities between the three records do exist. Notably, the rate of change of Sr/Ca is similar between 9 and 0 ka (−0.25%/kyr) and between 25 and 16 ka (+0.16%/kyr). This suggests that during these intervals, benthic foraminiferal Sr/Ca was affected by similar large-scale variables. One of these variables may be the average marine Sr/Ca ratio; however, comparison with model predictions [H.M. Stoll and D.P. Schrag, Geochim. Cosmochim. Acta 62 (1998) 1107–1118] suggests other factors must also be considered. The discrepancies between the two sites may be related to the different water mass histories for the Caribbean and eastern Atlantic. Our results suggest that variation of the seawater Sr budget only partially contributed to C. wuellerstorfi Sr/Ca records, while other significant factors still need to be quantified. At present we cannot confidently determine past seawater Sr/Ca variation from our foraminiferal records.  相似文献   

Sources, distribution and storage of heavy metals in the Río Pilcomayo, Bolivia     

Karen A. Hudson-Edwards  Mark G. Macklin  Jerry R. Miller  Paul J. Lechler 《Journal of Geochemical Exploration》2001,72(3)

The Río Pilcomayo rises on the Cerro Rico de Potosí precious metal-polymetallic tin deposits of Bolivia, and flows in a southeasterly direction for ca. 600 km to Bolivia's southern border with Argentina. Mining of the Potosí deposits has occurred continuously since 1545, generating large quantities of waste materials in the headwater of the basin. In addition, a tailings dam breach at the Porco mine in 1996 released an estimated 235 000 m³ of tailings and fluid into the upper reaches of the Río Pilaya, the largest tributary to the Pilcomayo.Concentrations of As, Sb, Cd, Cu, Pb, Hg, Ag, Tl and Zn in contemporary channel sediments upstream of the Pilaya confluence are significantly elevated above background values. Elevated levels appear to be associated with pyrite- and other sulphide mineral-bearing tailings materials transported more than 200 km downstream of the Potosí mines. Significant downstream declines in elemental concentrations occur within 15 km, and again between 150 and 200 km, from the mines. The initial decrease in concentrations is due to the rapid dilution of nearly pure tailings effluent released to the river from milling facilities near Potosí. The latter decrease results from a combination of geomorphic processes including the storage of sediment-borne metals within the channel bed and the influx of ‘clean’ sediment from several large tributaries. Downstream of the Pilaya confluence, concentrations of Cu, Pb, Hg and Zn are only slightly elevated above background values, and Ag, Cd, Sb and Tl cannot be distinguished from background levels. These data suggest that while the Porco tailings spill may have had a significant short-term impact on sediment and water quality along the lower reaches of the Río Pilcomayo, its longer-term impacts were limited. Metals stored and eroded from alluvial deposits of historical age in upstream reaches appear to be an important source of metals to the river today. An additional, and perhaps more significant source, is the release of tailings effluent to the river from modern milling operations. The transport of these contaminants downstream of Icla (203 km from Potosí) appears to be restricted by aggradational processes occurring in the vicinity of Puente Sucre. In addition, downstream of the confluence of the Río Pilaya, inputs of large amounts of ‘clean’ sediment have caused dilution of the metal contaminants. Data from other studies where similar geomorphic processes have occurred suggest that the metals in the upper Pilcomayo may eventually be moved downvalley as the aggradational processes are reversed and channel stabilisation occurs. Thus, the most significant impacts of metal contamination may not be realised in downstream areas for decades.  相似文献   

广西巴里—龙头山100号锡多金属矿床成矿物理化学环境研究——氧逸度(f_(o_2))、CO_2逸度(f_(co_2))、硫逸度(f_(s_2))、mΣs     

邓金灿  李蘅  徐文炘  曾文高  韦少校  韦万川  马文来  苏亚汝  甘文志  左湛松  韦汉蒙 《矿产与地质》2001,(3)

根据已知的 10 0号矿体的成矿温度及成矿压力 ,并结合矿体的矿物组合推算出10 0号矿体是在相对低硫、氧和二氧化碳逸度 ,溶液为酸性至弱碱性的物理化学环境下形成的。  相似文献   

河套华北地区旱涝的前期环流异常与大西洋海温的关系及其数值模拟   总被引：8，自引：1，他引：8  

陈晓光  徐祥德  朱乾根 《气象学报》1996,54(1):102-107

首先分析了河套华北地区旱涝的前期异常环流，然后探讨了这种异常环流形成的机制，最后采用了ＯＳＵ－ＡＧＣＭ作了大西洋地区热源异常强迫的数值试验。结果表明，大西洋地区海温异常强迫激发的定常波向上、下游的能量传播，造成的前期秋冬季环流异常与河套华北地区的夏季旱涝有较好的对应关系。  相似文献   

Surface NO and NO2 mixing ratios measured between 30° N and 30° S in the Atlantic region     

F. Rohrer  D. Brüning 《Journal of Atmospheric Chemistry》1992,15(3-4):253-267

Surface NO and NO₂ mixing ratios were measured aboard the research vessel Polarstern during the mission ANT VII/1 from 24 September to 5 October 1988. The measurements were taken along the meridian at 30° W in the Atlantic region covering latitudes between 30° N and 30° S. The average mixing ratios were about 12 pptv NO/30 pptv NO₂ in the Northern Hemisphere and about 7 pptv NO/22 pptv NO₂ in the Southern. Elevated mixing ratios of 20 pptv NO/70 pptv NO₂ were found at 12° N (probably due to air masses originating from the surface of West Africa) and in the region of the ITCZ between 8° N and 5° N. Because of probable contamination by the ship, the measured mixing ratios mostly represent upper limits.  相似文献   

吉林基性超基性岩的地质特征及找矿方向   总被引：3，自引：0，他引：3  

冯守忠  路瑞春 《矿产与地质》1992,6(3):183-187

从多旋回大地构造演化的观点,分析吉林区域多旋回的构造运动,控制多旋回的基性超基性岩浆活动及其相应的成矿作用,认为与含镍有关的基性超基性岩体,主要受“台槽边界”赤峰—开源深断裂控制,沿深断裂一侧或两侧成带分布,分群集中。为铜镍矿床区域勘查工作,提供地质资料。  相似文献